期刊
SCIENCE CHINA-MATERIALS
卷 63, 期 2, 页码 288-299出版社
SCIENCE PRESS
DOI: 10.1007/s40843-019-1170-7
关键词
high entropy alloys; CALPHAD; precipitation; mechanical properties; dislocations
资金
- Fundamental Research Funds for the Central Universities of Central South University [2019zzts052]
- National Natural Science Foundation of China [51828102]
Designing high entropy alloys (HEAs) with high strength and excellent ductility has attracted extensive scientific interest. In the present work, the CALPHAD (calculation of phase diagrams) method was applied to guide the design of an (FeCoNi)(92)Al2.5Ti5.5 HEA strengthened by precipitation hardening. The grain size as well as the size and volume fraction of the precipitates was tailored via a thermo-mechanical process to optimize the mechanical properties. The uniformly dispersed nano-precipitates are Ni-3(Al,Ti)-type precipitates with an LI2 ordered structure presenting a fully coherent interface with the face-centered cubic (FCC) matrix. The yield strength of the alloy increases from 338.3 to 1355.9 MPa and the ultimate tensile strength increases from 759.3 to 1488.1 MPa, while the elongation maintains a reasonable value of 8.1%. The striking enhancement of strength is mainly caused by the precipitate's hardening mechanism, which is evaluated quantitatively by various analytical models. The deformation-induced microbands and the coherent precipitates sheared by dislocations are the deformation and strengthening mechanisms contributing to the superior combination of ductility and strength in the present HEA. This investigation demonstrates that the CALPHAD method is beneficial to the design and optimization of HEAs.
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