Elemental Composition of Biochar Obtained from Agricultural Waste for Soil Amendment and Carbon Sequestration

For an agricultural country such as Thailand, converting agricultural waste into biochar offers a potential solution to manage massive quantities of crop residues following harvest. This research studied the structure and chemical composition of biochar obtained from cassava rhizomes, cassava stems and corncobs, produced using a patented locally-manufactured biochar kiln using low-cost appropriate technology designed to be fabricated locally by farmers. The research found that cassava stems yielded the highest number of Brunauer-Emmett-Teller (BET) surface area in the biochar product, while chemical analysis indicated that corncobs yielded the highest amount of C (81.35%). The amount of H in the corncob biochar was also the highest (2.42%). The study also showed biochar produced by slow pyrolysis was of a high quality, with stable C and low H/C ratio. Biochar's high BET surface area and total pore volume makes it suitable for soil amendment, contributing to reduced soil density, higher soil moisture and aeration and reduced leaching of plant nutrients from the rhizosphere. Biochar also provides a conducive habitat for beneficial soil microorganisms. The findings indicate that soil incorporation of biochar produced from agricultural crop residues can enhance food security and mitigate the contribution of the agricultural sector to climate change impacts.