期刊
ADVANCED SCIENCE
卷 7, 期 1, 页码 -出版社
WILEY
DOI: 10.1002/advs.201800178
关键词
bismuth; nanoplates; oxygen reduction reaction; platinum; tolerance
资金
- Ministry of Science and Technology [2016YFA0204100]
- National Key Research and Development Program of China [2016YFB0100201]
- National Natural Science Foundation of China [21571135, 51671003]
- Young Thousand Talented Program
- Soochow University
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
The crossover issue of small-molecule organic fuels usually makes the Pt-based nanocatalysts exhibit low efficiency, and poor tolerance and durability under the practical fuel cell operating conditions. Here, a new approach to prepare a class of intermetallic hexagonal PtBi nanoplates with superior tolerance over chemical fuels for boosting oxygen reduction catalysis is reported. The time-dependent morphology studies reveal that the well-defined hexagonal PtBi nanoplates are transformed from a new reaction immediate (triangular/truncated triangular bismuth oxides nanoplates). Different from conventional Pt-based catalysts, the hexagonal PtBi nanoplates exhibit much improved tolerance over CH3OH, HCOOH, and CO. X-ray photoelectron spectroscopy results reveal that the charge displacement resulting from Pt-Bi bonding is the main factor in enhancing the tolerance. The PtBi nanoplates also exhibit much higher ORR activity than all the reported PtBi nanoparticles. Considering their exceptional antipoisoning ability and high activity, these hexagonal nanoplates show great potential in the development of commercial fuel cells.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据