期刊
NANO ENERGY
卷 62, 期 -, 页码 55-63出版社
ELSEVIER
DOI: 10.1016/j.nanoen.2019.04.087
关键词
Lithium metal anode; Dendrite; ZnO nanosheet; MOF; Lithium battery
类别
资金
- National Key RAMP
- D Program of China [2016YFF0204302]
- National Natural Science Foundation of China [51872305]
- Key RAMP
- D Program of Zhejiang Province [2018C01049]
The safety issue and poor stability induced by dendrite growth and volume change present major barriers to the practical application of lithium-metal anode for next-generation high-energy-density batteries. Herein, we propose vertically aligned ZnO nanosheets derived from zinc-based MOF grown on Ni foam (LZNF) as a lithiophilic porous scaffold to mitigate these problems. The interspace between the cross-linked ZnO nanosheets as the lithiophilic reservoir enables homogenous plating/stripping of Li at a high deposition capacity of 15 mAh cm(2), which is difficult to realize on Ni foam substrate decorated with normal ZnO particles. The integration of vertically aligned ZnO nanosheets and 3D conductive Ni foam can not only induce dendrite-free lithium deposition with reduced current density but also alleviate the volume fluctuations of lithium. Consequently, a high Coulombic efficiency in LZNF/Li half-cell (98.5% for 150 cycles at 1 mA cm(-2)) and enhanced cycling stability of a symmetric LZNF@Li/LZNF@Li cell (5 mA cm(-2) for 250 cycles) with a small voltage hysteresis (45 mV) can be achieved. Our investigation shows that LZNF can serve as a promising multi-functional 3D host for dendrite-free Li metal anodes.
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