期刊
POLYMERS
卷 11, 期 8, 页码 -出版社
MDPI
DOI: 10.3390/polym11081357
关键词
polyaniline; branched nanofibers; redox-active gel electrolyte; flexible supercapacitor
资金
- Fundamental Research Funds for the Central Universities of China [21618408]
In this work, the effects of utilizing an Fe2+/Fe3+ redox-active electrolyte and Fe2+-doped polyaniline (PANI) electrode material on the performance of an assembled supercapacitor (SC) were studied. The concentration of the redox couple additive in the electrolyte of the SC was optimized to be 0.5 M. With the optimized concentration of 0.4 M Fe2+, the doped PANI branched nanofibers electropolymerized onto titanium mesh were much thinner, cleaner, and more branched than normal PANI. A specific capacitance (C-s) of 8468 F g(-1) for the 0.4 M Fe2+/PANI electrode in the 1 M H2SO4 + 0.5 M Fe2+/Fe3+ gel electrolyte and an energy density of 218.1 Wh kg(-1) at a power density of 1854.4 W kg(-1) for the resultant SC were achieved, which were much higher than those of the conventional PANI electrode tested in a normal H2SO4 electrolyte (404 F g(-1) and 24.9 Wh kg(-1)). These results are among the highest reported for PANI-based SCs in the literature so far and demonstrate the potential effectiveness of this strategy to improve the electrochemical performance of flexible SCs by modifying both the electrode and electrolyte.
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