期刊
ACS MACRO LETTERS
卷 8, 期 9, 页码 1075-1079出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.9b00498
关键词
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资金
- Ministry of Research and Education of the Russian Federation [14.W03.31.0022]
- National Science Foundation [DMR 1407645, DMR 1436201]
Theory of microphase segregation in the melt of diblock copolymers comprising two strongly incompatible blocks of similar or different topologies is developed. The spectrum of considered architectures include copolymers with arbitrary combinations of bottlebrush-like, dendritic, cycled blocks, and so on. Our theory provides quantitative predictions of how the morphology of the microphase segregated structures can be controlled not only by the volume fractions of the incompatible blocks, but also by their architecture. These predictions open perspectives for developing new materials, for example, photonic crystals, with independently adjustable volume fractions and morphology of the domains.
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