期刊
ADVANCED ENERGY MATERIALS
卷 9, 期 40, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201902123
关键词
critical current density; LiBH4; LiF; lithium dendrites; solid state electrolytes
类别
资金
- National Natural Science Foundation of China [51871059, 51601040, 51571063]
- National Major Scientific Research Equipment of China [51727801]
- National Key Research and Development Program of China [2017YFA0403703]
All-solid-state lithium metal batteries (ASSLMBs) stand out for the next generation of energy storage system. However, the further realization is severely hampered by the lithium dendrite formation in solid state electrolytes (SSEs), by mechanisms that remain controversial. Herein, with the aid of experimental and theoretical approaches, the origin of dendrite formation in representative LiBH4 SSE, which is thermodynamically stable with the Li metal, suppressing the side reaction between Li and SSE is elucidated. It is demonstrated that upon diffusion, Li+ encounters an electron, and is subsequently reduced to Li-0 within the grain boundary/pore of SSE, eventually leading to short circuit. Thus, introducing LiF with the ability of interstitial filling and low electronic conductivity into SSE is the effective countermeasure, and as expected, with the addition of LiF, the critical current density (CCD) increases by 235% compared to the value of pure LiBH4. The TiS2|LiBH4-LiF|Li ASSLMBs manifest a reversible capacity of 137 mAh g(-1) at 0.4 C upon 60 cycles. These findings not only unravel critical issues in Li dendrite formation in SSE, but also propose the countermeasure.
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