期刊
ADVANCED ENERGY MATERIALS
卷 9, 期 36, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201901213
关键词
CoP; NiCoP; heterojunction interface construction; hydrogen revolution electrocatalysis; nanocrystals synthesis; supercapacitors
类别
资金
- Fundamental Research Funds for the Central Universities [19CX02008A]
- China Postdoctoral Science Foundation [2018M642726]
- National Natural Science Foundation of China [21471160, 21701002]
- Taishan Scholars Program of Shandong Province
Constructing well defined nanostructures is promising but still challenging for high-efficiency catalysts for hydrogen evolution reaction (HER) and energy storage. Herein, utilizing the differences in surface energies between (111) facets of CoP and NiCoP, a novel CoP/NiCoP heterojunction is designed and synthesized with a nanotadpoles (NTs)-like morphology via a solid-state phase transformation strategy. By effective interface construction, the disorder in terms of electronic structure and coordination environment at the interface in CoP/NiCoP NTs is created, which leads to dramatically elevated HER performance within a wide pH range. Theoretical calculations prove that an optimized proton chemisorption and H2O dissociation are achieved by an optimized phosphide polymorph at the interface, accelerating the HER reaction. The CoP/NiCoP NTs are also proved to be excellent candidates for use in supercapacitors (SCs) with a high specific capacitance (1106.2 F g(-1) at 1 A g(-1)) and good cycling stability (nearly 100% initial capacity retention after 1000 cycles). An asymmetric supercapacitor shows a high energy density (145 F g(-1) at 1 A g(-1)) and good cycling stability (capacitance retention is 95% after 3200 cycles). This work provides new insights into the catalyst design for electrocatalytic and energy storage applications.
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