期刊
WASTE MANAGEMENT
卷 97, 期 -, 页码 140-148出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.wasman.2019.08.004
关键词
Spent lithium-ion batteries; LiCoO2; Recovery; Regeneration; Vacuum pyrolysis
资金
- Fundamental Research Funds for the Central Universities [N172505002]
- NSFC [51704060]
- National Thousand Youth Talent Program of China
- 111 Project [B16009]
An environmentally benign vacuum pyrolysis (VP) approach is employed to recover Li and Co from spent LiCoO2-based lithium-ion batteries (LIBs). First, the electroactive materials were separated from the current collector by the VP method from 623 to 823 K with an attempt to choose an appropriate temperature. Then, the as-received cathode materials were mixed with different amounts of graphite from the anode to selectively convert LiCoO2 to Co or CoO and Li2CO3 by carbothermic reduction under vacuum and at 873 to 1273 K. After carbothermic reduction, the pyrolyzed powder was leached in water to separate Li2CO3 from Co/CoO. By alternating the C/LiCoO2 mass ratio and the pyrolysis temperature, a recovery rate reaches over 93% for Li and 99% for Co. Finally, the recovered CoO and Li2CO3 were used to regenerated LiCoO2 that delivered a specific capacity of 145 mAh g(-1) at 1C and retaining 93% of the initial capacity after 100 cycles. Overall, a multi-vacuum-pyrolysis approach offers a closed-loop route for the management of spent LIBs without using any hazardous chemicals. (C) 2019 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据