期刊
TETRAHEDRON LETTERS
卷 60, 期 35, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2019.150973
关键词
Sesquiterpene; Sustrodorane; Asymmetric synthesis; Oxidative ring contraction
资金
- Natural Science Foundation of China [201702166, 21722206]
- Scientific Startup Foundation for Doctors of Northwest AF University [Z109021702]
Asymmetric synthesis of the marine nor-sesquiterpenoid (+)-austrodoric acid and (+)-austrodoral in seven and nine steps respectively from Wieland-Miescher ketone was described herein. The synthesis featured an oxidative ring contraction of alpha-formyl cyclic ketone mediated by H2O2 to forge the hydrindane scaffold together with the contiguous quaternary carbon centers simultaneously. (C) 2019 Elsevier Ltd. All rights reserved.
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