期刊
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
卷 12, 期 -, 页码 1877-1883出版社
BEILSTEIN-INSTITUT
DOI: 10.3762/bjoc.12.177
关键词
norbornene; propellane derivatives; ring-closing metathesis; single-crystal X-ray diffraction; vicinal diallylation
资金
- Department of Science and Technology (DST), New Delhi
- Department of Science and Technology
- University Grants Commission (UGC), New Delhi
Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.
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