期刊
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷 64, 期 9, 页码 1186-1189出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023619090213
关键词
electrolyte solutions; aluminum chloride; aluminum sulfate; dielectric permittivity; solvation
资金
- Russian Foundation for Basic Research [19-03-00033]
- Kurnakov Institute of General and Inorganic Chemistry
Activity coefficients are calculated for aqueous aluminum chloride and aluminum sulfate solutions at 298 K in terms of the generalized Debye-Huckel (DH) theory using experimental static dielectric permittivity versus concentration relationships. A semiquantitative fit of the experimental data is achieved; specifically, nonmonotonic activity coefficient versus concentration trends are reproduced. The applicability of the generalized Debye-Huckel theory to fit the thermodynamic properties of 3,1 and 3,2 valence type electrolytes is shown.
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