Complex [Ag(PPh3)(4)][2-B10H9NH3 center dot 2DMF]: Synthesis and Structure

The formation of complex salt [Ag(PPh3)(4)][2-B10H9NH3 center dot 2DMF] (I) by the reaction of the salts of the [2-B10H9NH3](-) anion with [Ag(PPh3)(4)]NO3 is studied. The anionic moiety of complex I is a stable solvate linked by hydrogen bonds of two types. Compound I is identified by IR spectroscopy and elemental, X-ray structure, and X-ray diffraction analyses (CIF file CCDC no. 1884451).