期刊
ORGANOMETALLICS
卷 38, 期 17, 页码 3322-3326出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.9b00394
关键词
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资金
- U.S. Department of Energy [FG02-86ER-13569]
- NSF GRFP award [DGE-1419118]
The efficient and atom-economical hydroboration of alkenes and alkynes using an N-heterocyclic carbene (NHC) copper hydroxide catalyst has been developed. An equimolar combination of substrate and HBpin allows for the selective Markovnikov hydroboration of alkenes and alkynes. A variety of functional groups were tolerated in good to excellent yield. This system features a facile reaction setup, atom economy, high selectivity, and an easily synthesized copper-NHC catalyst.
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