期刊
ORGANIC LETTERS
卷 21, 期 17, 页码 6835-6838出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02475
关键词
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资金
- Natural Science Foundation of China [21273024]
- Sci-Tech Development Project of Jilin Province in China [20170101095JC]
- Foundation of Jilin Educational Committee [JJKH20180244KJ, JJKH20181091KJ]
- China Postdoctoral Science Foundation [2016M601355]
- Norman Bethune Program of Jilin University [2015330]
- Changchun Discovery Sciences, Ltd.
A nickel-catalyzed electrochemical cross-coupling reaction of aryl bromides with dialkyl phosphites, ethyl phenylphosphinate, and diphenylphosphine oxide has been developed. This reaction utilizes a simple undivided cell with inexpensive carbon electrodes to synthesize aryl phosphonates, aryl phosphinates, and arylphosphine oxides at room temperature. This protocol provides a mild and efficient route for the construction of C-P bond in moderate to high yields with broad substrate scope.
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