期刊
ORGANIC LETTERS
卷 21, 期 17, 页码 6690-6694出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02306
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资金
- DST-India [DST/SJF/CSA-01/2015-16]
- DST-India
- CSIR-India
- CSIR, India
This work discloses transamidation of primary and tertiary amides with a range of aryl, heteroaryl, and aliphatic amines using potassium tert-butoxide. The reaction proceeds at room temperature under transition-metal-free conditions providing secondary amides in high yields. Moreover, reaction of cyclopropyl amine with tertiary amides proceeds with ring-opening to provide a rapid access to enamides.
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