期刊
ORGANIC LETTERS
卷 21, 期 18, 页码 7430-7434出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02740
关键词
-
资金
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- National Natural Science Foundation of China [21072143]
A new generation method of N-centered radicals from the reductive cleavage of the N-O bond in oxime ether promoted by SmI2 is reported for the first time. The in-situ-generated N-centered radicals underwent intramolecular cyclization to afford five-membered cyclic imines in two manners: N-centered radical addition and N-centered anion nucleophilic substitution. From a synthetic point of view, an efficient synthetic method of five-membered cyclic imines was developed. A mechanism of the transformation was proposed.
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