期刊
ORGANIC LETTERS
卷 21, 期 19, 页码 8138-8143出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b03243
关键词
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资金
- NISER
- Department of Atomic Energy (DAE)
- Council for Scientific and Industrial Research (CSIR), New Delhi [02(0256)/16/EMR II]
- Science and Engineering Research Board (SERB), New Delhi [EMRII/2017/001475]
- DAE
Herein, we disclosed the first report on the selective C(4)-H functionalization of 3-acetylindole derivatives using first-row transition metal cobalt where an acetyl group is acting as a weakly coordinating directing group. Selective C(4)-H functionalization has been achieved using diverse Michael acceptors (acrylate and maleimide) simply by switching the additive from copper acetate to silver carbonate. Further the formation of acobaltacycle intermediate was also detected through HRMS for mechanistic insight.
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