期刊
ORGANIC LETTERS
卷 21, 期 19, 页码 7726-7730出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02569
关键词
-
资金
- National Natural Science Foundation of China [U1610104, 21676046]
The selective oxidation of olefins, in particular, aromatic olefins to carbonyls, is of significance in organic synthesis. In general, stoichiometric toxic oxidants or a high-cost catalyst is required. Herein we report a novel and practical light-enabled protocol for the synthesis of carbonlys in high yield through a catalyst-free oxidation of olefins using H2O2 as a clean oxidant. A broad scope of carbonyls can be synthesized in high yield, and no catalyst or toxic oxidant is required.
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