期刊
ORGANIC LETTERS
卷 21, 期 18, 页码 7303-7306出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02584
关键词
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资金
- Chinese NSF [21702216, 81773565]
- NST Major Project Key New Drug Creation and Manufacturing Program China [2018ZX09711002-006-003]
- China Postdoctoral Science Foundation [2018T110416, 2017M621566]
- Sanofi-SIBS 2017 Postdoctoral Fellowship
Aryl-heteroatom bonds (C-Het) are almost ubiquitously present in chemical molecules. However, methods for diverse C-Het bond formations from a simple substrate are limited. Herein, we report a convenient and efficient C-S bond transformation of aryl sulfoniums to various C-Het bonds (C-O, C-S, C-Sn, C-Si, C-Se) in the absence of any transition-metal catalyst. These reactions proceeded in mild conditions with a wide substrate scope.
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