期刊
ORGANIC LETTERS
卷 21, 期 18, 页码 7587-7591出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02862
关键词
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资金
- National Natural Science Foundation of China [21672177, 21931010]
- National Key R&D Program of China [2017YFA0207302]
- Natural Science Foundation of Fujian Province of China [2016J01074, 2017J01021]
- NFFTBS [J1310024]
- PCSIRT of the Ministry of Education, China
We report the first catalytic, enantioselective reductive bis-functionalization of common amides, which provides a facile access to a variety of 2,2-disubstituted 3-iminoindolines in good yields and with excellent enantioselectivities. The reaction conditions are quite mild and can be run on a gram scale. In this one-pot reaction, three C-C bonds, one ring, and one nitrogen-containing tetrasubstituted carbon stereocenter are created in a catalytic enantioselective manner.
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