期刊
ORGANIC LETTERS
卷 21, 期 20, 页码 8174-8177出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02634
关键词
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资金
- National Natural Science Foundation of China [41676130, 21772164]
- Xiamen Southern Oceanographic Center [17GYY026NF0S]
An intriguing cage-like polyhemiketal, nesteretal A (1), was isolated from the coral-derived actinomycete Nesterenkonia halobia. Its structure was established by extensive spectroscopic and computational methods. Nesteretal A is a highly oxygenated compound featuring an unprecedented 5/5/5/5 tetracyclic scaffold. A possible biosynthetic pathway of 1 from naturally occurring diacetyl was proposed. Compound 1 showed a weak retinoid X receptor-alpha (RXR alpha) transcriptional activation effect.
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