A New Series of EDOT Based Co-Sensitizers for Enhanced Efficiency of Cocktail DSSC: A Comparative Study of Two Different Anchoring Groups

Herein, we report the design and synthesis strategy of a new class of five EDOT based co-sensitizers (CSGR1-5) by introducing different donors (2,3,4-trimethoxypheny, 2,4-dibutoxyphenyl, and 2,4-difluorophenyl) and anchoring groups (rhodamine-3-acetic acid and cyanoacetic acid) systematically. The synthesized metal-free organic co-sensitizers were employed for cocktail dye-sensitized solar cells along with N749 (black dye). The DSSC devices with a mixture of co-sensitizers (CSGR1-5) and N749 have shown a 7.95%, 8.40%, 7.81%, 6.56% and 6.99% power conversion efficiency (PCE) respectively, which was more than that of single N749 dye PCE (6.18%). Enhanced efficiency could be ascribed to the increased short circuit current (J(sc)) and open circuit voltage (V-oc). The increased J(sc) was achieved due to enhanced light harvesting nature of N749 device upon co-sensitization with CSGR dyes and feasible energy levels of both the dyes. The V-oc was improved due to better surface coverage which helps in decreasing the rate of recombination. The detailed optical and electrochemical properties were investigated and complimented with theoretical studies (DFT).