期刊
MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS
卷 102, 期 -, 页码 708-717出版社
ELSEVIER
DOI: 10.1016/j.msec.2019.04.072
关键词
Electrochemical sensor; Nitrogen doped holey graphene; NiCo2O4 nanoflowers; Non-enzymatic; Glucose; Hydrogen peroxide
资金
- Science and Technology program of Guangdong Province [2019B020219002, 2018A050506006]
- Guangdong Natural Science Foundation [2017A030312005]
- National Natural Science Foundation of China (NSFC) [21875070]
In this work, a simple strategy for fabricating a 3D nitrogen doped holey graphene hydrogel decorated with NiCo2O4 nanoflowers (NHGH/NiCo2O4) via a one-pot hydrothermal method with subsequent calcination is reported for the first time. The novel NHGH/NiCo2O4 nanocomposites featured high electrical conductivity, large and accessible surface areas, abundant active sites, and excellent electrocatalytic performance. Considering the excellent catalytic activity of NiCo2O4, a sensitive and bifunctional electrochemical non-enzymatic biosensor was established for the determination of glucose and hydrogen peroxide (H2O2). The obtained biosensor exhibited wide linear ranges (glucose: 0.005-10.95 mM; H2O2: 1-510 tiM) and a low detection limits (glucose: 0.39 mu M; H2O2: 0.136 mu M) in alkaline solution (S/N = 3). Excellent electrocatalytic activity of this sensor was ascribed to the synergistic effects of the hybrid structure between the NiCo2O4 nanoflowers and NHGH. Furthermore, the sensitive biosensor also exhibited high selectivity and could be applied to determine glucose in real blood samples. Taken together, the results reveal that the proposed hybrid nanocomposite could be a promising electrochemical biosensor.
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