期刊
MACROMOLECULAR RESEARCH
卷 28, 期 1, 页码 74-81出版社
POLYMER SOC KOREA
DOI: 10.1007/s13233-020-8018-z
关键词
benzoxazine; 3-methytetrahydrophtalimide; nitrile; thermal properties
Two 3-methytetrahydrophtalimide-functional benzoxazine monomers containing nitrile group have been prepared in order to achieve the basic design rules for developing high-performance thermosets via multifunctional benzoxazines. The chemical structures of the two new synthesized benzoxazine monomers have been confirmed by H-1 NMR, C-13 NMR and FT-IR. Besides, the polymerization behavior has been studied by using DSC and in situ FT-IR. In addition, the thermal stability and flame retardant properties of the resulting polybenzoxazines have also been investigated using TGA and MCC. The polybenzoxazine based on ortho-3-methytetrahydrophtalimide functional benzoxazine containing ortho-nitrile group exhibits excellent thermal stability and low flammability, with a T-d10 of 378 degrees C and a HRC value of 180 J/(g K).
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