期刊
MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 220, 期 20, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.201900219
关键词
biocatalysis; carbohydrates; glycomonomers; horseradish peroxidase; beta-glucosidase
资金
- Indonesia Endowment Fund for Education (Lembaga Pengelola Dana Pendidikan Republik Indonesia/LPDP RI)
beta-Glucosidase and horseradish peroxidase (HRP) are used as biocatalysts in aqueous solution for the enzymatic synthesis of glycomonomers and the respective enzymatic polymerization toward glycopolymers. The biocatalytically synthesized monomers contain (meth)acrylate functionalities that are able to be polymerized by an enzyme-initiated polymerization using an HRP/hydrogen peroxide/acetylacetone ternary system. The structure of the glycomonomers and the respective glycopolymers as well as the monomer conversion after the reaction are determined by H-1 NMR spectroscopy. The synthesized glycopolymers have a dispersity and a number-average molecular weight up to 5.8 and 297 kg mol(-1), respectively. Thermal and degradation properties of the glycopolymers are studied by differential scanning calorimetry and thermogravimetric analysis. In addition, preparation of glycopolymers via conventional free radical polymerization is performed and the properties of the obtained polymers are compared with the enzymatically synthesized glycopolymers.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据