期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 32, 页码 12872-12879出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b06383
关键词
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资金
- National Science Foundation (NSF) [CHE-1111563]
- Australian Research Council
- Australian National Computing Infrastructure
- Rackham Graduate School
- NSF [CHE-0840456]
- NSERC
This Article describes the development of a stable Ni-IV complex that mediates C(sp(2)) - H trifluoromethylation reactions. This reactivity is first demonstrated stoichiometrically and then successfully translated to a Ni-IV-catalyzed C-H trifluoromethylation of electron-rich arene and heteroarene substrates. Both experimental and computational mechanistic studies support a radical chain pathway involving Ni-IV, Ni-III, and Ni-II intermediates.
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