期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 37, 页码 14480-14485出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b03296
关键词
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资金
- Cornell University
- NIGMS [R01GM130928]
- NSF [CHE-1531632]
In contrast to the rapid growth of synthetic electrochemistry in recent years, enantioselective catalytic methods powered by electricity remain rare. In this work, we report the development of a highly enantioselective method for the electrochemical cyanophosphinoylation of vinylarenes. A new family of serine-derived chiral bisoxazolines with ancillary coordination sites were identified as optimal ligands.
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