期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 33, 页码 13261-13267出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b06896
关键词
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资金
- National Science Foundation [CHE-1111563]
- Australian Research Council
- Australian National Computing Infrastructure
- Rackham Graduate School (RMF)
- NSF [CHE-0840456]
The treatment of pyridine- and pyrazole-ligated Ni-II sigma-aryl complexes with Selectfluor results in C(sp(2))-F bond formation under mild conditions. With appropriate design of supporting ligands, diamagnetic Ni-IV sigma-aryl fluoride intermediates can be detected spectroscopically and/or isolated during these transformations. These studies demonstrate for the first time that Ni-IV sigma-aryl fluoride complexes participate in challenging C(sp(2))-F bond-forming reductive elimination to yield aryl fluoride products.
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