期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 123, 期 34, 页码 21083-21096出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.9b06811
关键词
-
资金
- European Union's INTERREG VA Programme
- Department for the Economy in Ireland
- Science Foundation Ireland through the ERA-NET for Materials Research and Innovation (M-ERA.Net 2)
- Horizon 2020 Grant [685451]
- SFI [SFI/16/M-ERA/3418]
- SFI/HEA
- COST Action Reducible Metal Oxides, Structure and Function [CM1104]
- VCRS scholarship from Ulster University
- Invest Northern Ireland [RD071392]
- SFI
- Department of Jobs, Enterprise and Innovation in Ireland
The thermal stability of anatase titanium dioxide (TiO2) is a prerequisite to fabricate photocatalyst-coated indoor building materials for use in antimicrobial and self-cleaning applications under normal room light illumination. Metal doping of TiO2 is an appropriate way to control the anatase to rutile phase transition (ART) at high processing temperatures. In this work, ART of indium (In)-doped TiO2 (In-TiO2) was investigated in detail in the range of 500-900 degrees C. In-TiO2 (In mol % = 0-16) was synthesized via a modified sol-gel approach. These nanoparticles were further characterized by means of powder X-ray diffraction (XRD), Raman, photoluminescence (PL), transient photocurrent response, and X-ray photoelectron spectroscopy (XPS) techniques. XRD results showed that the anatase phase was maintained up to 64% by 16 mol % of In doping at 800 degrees C of calcination temperature. XPS results revealed that the binding energies of (Ti 2p(1/2 )and Ti 2p(3/2)) were red-shifted by In doping. The influence of In doping on the electronic structure and oxygen vacancy formation of anatase TiO2 was studied using density functional theory corrected for on-site Coulomb interactions (DFT+U). First-principles results showed that the charge-compensating oxygen vacancies form spontaneously at sites adjacent to the In dopant. DFT+U calculations revealed the formation of In - Ss states in the band gap of the anatase host. The formation of In2O3 at the anatase surface was also examined using a slab model of the anatase (101) surface modified with a nanocluster of composition In4O6. The formation of a reducing oxygen vacancy also has a moderate energy cost and results in charge localization at In ions of the supported nanocluster. PL and photocurrent measurements suggested that the charge carrier recombination process in TiO2 was reduced in the presence of In dopant. The photocatalytic activity of 2% In-TiO2 calcined at 700 degrees C is more comparable with that of pure anatase.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据