期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 21, 页码 13549-13556出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01813
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资金
- Universita di Roma La Sapienza (Progetti di ricerca grandi 2017)
The oxidation of a series of hydrocarbons by the nonheme iron(IV)-oxo complex [(N4Py)Fe-IV=O](2+) is efficiently mediated by N-hydroxyphthalimide. The increase of reactivity is associated to the oxidation of the mediator to the phthalimide N-oxyl radical, which efficiently abstracts a hydrogen atom from the substrates, regenerating the mediator in its reduced form.
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