期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 20, 页码 13172-13178出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01775
关键词
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资金
- Nanyang Technological University
- Singapore Ministry of Education [MOE2016-T2-2-043]
A cobalt-catalyzed ortho-C-H benzylation reaction of pivalophenone N-H imines with benzyl phosphates is reported. The reaction is promoted at room temperature by a ternary catalytic system comprising Co(acac)(3), a pyridylphosphine ligand, and a Grignard reagent and tolerates a series of substituted pivalophenone imines and benzyl phosphates moderate yields.
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