期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 20, 页码 13013-13021出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01815
关键词
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资金
- National Basic Research Program of China [21472165, 21672186, 21602202]
- Important Project of Zhejiang Province [2017C03049]
A rhodium-catalyzed redox-neutral reaction of arylhydrazines with sulfoxonium ylides to construct 2-arylindole derivatives in one pot has been developed. The transformation proceeds efficiently under mild conditions and. involves tandem C-H activation and an intramolecular dehydration annulation sequence, providing a straightforward pathway to access pharmaceutically and biologically valuable 1-aminoindole derivatives.
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