期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 20, 页码 12722-12745出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02428
关键词
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资金
- NSF under the CCI Center for Selective C-H Functionalization [CHE-1700982]
- NSF [CHE 1465189]
- NIH [GM-099142]
Catalyst-controlled C-H functionalization by means of the C-H insertion chemistry of rhodium carbenes has become a powerful synthetic method. The key requirements for the development of this chemistry are donor/acceptor carbenes and the chiral dirhodium tetracarboxylate catalysts. This perspective will describe the stages involved in developing this chemistry and illustrate the scope of the donor/acceptor carbene C-H functionalization.
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