4.7 Article

Synthetic Studies on FNC-RED and Its Analogues Containing an All syn-Cyclopentanetetrol Moiety

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JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 19, 页码 12680-12685

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AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02101

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  1. [JP26282211]
  2. [JP16H01162]
  3. [JP17H02207]
  4. [JP18H04426]
  5. [JP26882036]
  6. [JP16K16638]

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FNC-RED exhibits innate immune receptor Toll-like receptor 4 (TLR4)/myeloid differentiation factor-2 (MD2) stimulatory activity. We have developed a divergent synthetic route to FNC-RED derivatives containing various alkyl side chains. Key features of the synthetic study include stepwise palladium catalyzed cross-coupling reactions and the construction of an all syn-cyclopentanetetrol moiety.

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