期刊
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 38, 期 -, 页码 47-55出版社
JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2019.07.043
关键词
Mg-air batteries; Magnesium alloy; Discharge performance; Electrochemical behaviors; Ultrasonic field; Electromagnetic field
资金
- National Key Research and Development Program of China [2016YFB0301104]
- National Natural Science Foundation of China [51974082]
- Programme of Introducing Talents of Discipline Innovation to Universities 2.0 (the 111 Project of China 2.0) [BP0719037]
In this work, the effects of external field treatment on electrochemical behaviors and discharge performance of as-cast Mg-8%Al-0.5%Zn (wt%) anodes for Mg-air batteries are systematically investigated in 3.5 wt% NaCl solution. The external field treatment particularly the variable-frequency ultrasonic field can dramatically refine the alpha-Mg grains and beta phases. The grain size decreases from 1594.8 + 43 mu m (untreated billet) to 140.6 + 15 mu m after variable-frequency ultrasonic field treatment. The values of open circuit potential, electrochemical activity and corrosion resistance of Mg-8%Al-0.5%Zn anode are improved with external field treatment, which should be attributed to refined grains and dispersive p phase. The external field treatment especially the variable-frequency ultrasonic field improves stability and the value of cell voltage, and enhances the discharge performance of the Mg-8%Al-0.5%Zn anode. The variable-frequency ultrasonic field treated anode has the best discharge capacity and anodic efficiency at current density of 45 mA cm(-2), with the values of 1417 mA h g(-1) and 63.3%, respectively. The ultrasonic field vibration changes the dissolution behavior of alpha-Mg matrix during the discharge process, showing the oriented surface morphologies. (C) 2019 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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