4.7 Article

Biopolymer phytagel-derived porous nanocarbon as efficient electrode material for high-performance symmetric solid-state supercapacitors

期刊

出版社

ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2019.08.003

关键词

Biopolymer; Hydrothermal; Porous carbon; Electrochemical properties

资金

  1. Ministry of Trade, Industry and Energy (MOTIE, Korea) under Sensor Industrial Technology Innovation Program [10063682]
  2. Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2017R1D1A1A09000823]
  3. European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant [713683]

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In the present work, a porous nano-carbon (PNC) based electrode materials were successfully derived from the natural biopolymer phytagel via a facile hydrothermal and combustion process. The carbon phase structure of the PNC electrode was confirmed using different spectroscopy, microscopy and N-2 adsorption-desorption analyses. The surface morphology investigation showed a distinct shape and size for the PNC that demonstrated its porous nature. The electrochemical performance of PNC was completely reliant on the calcination temperature (800 degrees C) and it delivered the maximum capacitance of 122 Fg(-1) at 0.25 Ag-1. An AC impedance and cyclic voltammetry analyses proved the intrinsic electrochemical behavior by their cycling. Besides, the fabricated symmetric solid-state supercapacitor displayed an outstanding cycle durability with a stable capacitance retention of 85.8% over 8000 cycles, suggesting favorable prospects for its use as an active candidate for symmetric solid-state supercapacitor applications. (C) 2019 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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