期刊
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
卷 137, 期 -, 页码 420-425出版社
ELSEVIER
DOI: 10.1016/j.ijbiomac.2019.06.185
关键词
Sodium alginate; Acrylonitrile; Nanofibers; Electrospinning
资金
- National Natural Science Foundation of China [51773024]
- Liaoning Science and Technology Innovation Team Project of China [L12017017]
In this work, to improve the spinnability of sodium alginate, potassium persulfate (KPS) was used as initiator, SA was modified with acrylonitrile (AN) to prepare sodium alginate-polyacrylonitrile copolymer (SA-g-AN), and SA-g-AN/PEG composite solutions were prepared by blending SA-g-AN and polyethylene glycol (PEG) as spinning solution to prepare corresponding electrospun nanofibers. The chemical structure and thermal stability of SA g-AN were characterized by infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC). The physical properties of SA-g-AN and SA-g-AN/PEG spinning solution were determined by viscometer, surface tension meter and electrical conductivity meter, the morphology of SA-g-AN and SA-g-AN/PEG electrospun fibers were observed by scanning electron microscopy (SEM). And the oil-water separation performance and water resistance of SA-g-AN electrospun fibers were also investigated. The results revealed that: the graft modification of acrylonitrile significantly improved the electrospinnability of sodium alginate. The water-resistance of modified graft copolymer was improved as well as the thermal stability, and the electrospun nanofibers had a uniform morphology and stable oil-water separation performance. (C) 2019 Elsevier B.V. All rights reserved.
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