期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 112, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.inoche.2019.107544
关键词
Alcohol oxidation; Carbonyl compounds; Ruthenium-terpyridine; Molecular oxygen; Mild conditions
资金
- National Key Research and Development Program of China [2016YFA0602900]
- National Natural Science Foundation of China [21576302, 21878344, 21425627]
- Guangdong Technology Research Center for Synthesis and Separation of Thermosensitive Chemicals [2015B090903061]
- Science and Technology Innovation Teams Project of Huizhou [20131226121851953]
The oxidation of alcohols with molecular oxygen is a promising approach to produce corresponding carbonyl compounds. In this work, efficient aerobic oxidation of alcohols to carbonyl compounds catalyzed by ruthenium-terpyridine [(tpy-PhCH3)RuCl3] with isobutyraldehyde as co-substrate was developed. Various alcohols including primary and secondary alcohols are smoothly converted to corresponding carbonyl compounds in good yield. In a 100 times large-scale oxidation of benzyl alcohol, benzaldehyde was obtained with 92% isolated yield. Moreover, a plausible mechanism involving high-valence ruthenium species was proposed based on in situ UV-vis spectroscopy.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据