期刊
INORGANIC CHEMISTRY
卷 58, 期 17, 页码 11274-11278出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b01377
关键词
-
资金
- SERB (DST), India [EMR/2017/000772]
- SERB (DST) [PDF/2016/000275, PDF/2017/001355]
The reduction of nitriles to primary amines using an inexpensive silane such as polymethylhydrosiloxane (PMHS) is an industrially important reaction. Herein we report the synthesis of an earth-abundant Fe(III) complex bearing a phenalenyl-based ligand that was characterized by mass spectroscopy, elemental analysis, cyclic voltammetry, and single-crystal X-ray diffraction. The complex showed excellent catalytic activity toward reduction of aromatic, heteroaromatic, aliphatic, and sterically crowded nitriles to produce primary amines using polymethylhydrosiloxane (PMHS).
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