期刊
INORGANIC CHEMISTRY
卷 58, 期 17, 页码 11553-11560出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b01402
关键词
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资金
- UGC
- SERB, New Delhi [ECR/2015/000041]
In the context of porous crystalline materials toward CO2 separation and capture, a new 2-fold interpenetrated 3D microporous Co-MOF, IITKGP-11 (IITKGP denotes Indian Institute of Technology Kharagpur), has been synthesized consisting of a 1D channel of similar to 3.6 X 5.0 angstrom(2) along the [101] direction with a cavity volume of 35.20%. This microporous framework with a BET surface area of 253 m(2)g(-1) shows higher uptake of CO2 (under 1 bar, 3.35 and 2.70 mmol g(-1) at 273 and 295 K, respectively), with high separation selectivities for CO2/N-2 and CO2/CH4 gas mixtures under ambient conditions as estimated through LAST calculation. Moreover, real time dynamic breakthrough studies reveal the high adsorption selectivity toward CO(2)( )for these binary mixed gases at 295 K and 1 bar. Besides high gas separation selectivity, capacity considerations in mixed gas phases are also important to check the performance of a given adsorbent. CO2 loading amounts in mixed gas phases are quite high as predicted through LAST calculation and experimentally determined from dynamic breakthrough studies. In order to get insight into the phenomena, GCMC simulation was performed demonstrating that the CO2 molecules are electrostatically trapped via interactions between oxygen on CO2 and hydrogen on pyridyl moieties of the spacers.
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