期刊
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 58, 期 37, 页码 17489-17506出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.9b02817
关键词
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资金
- DETEC (CH) [271498]
- BMWi (DE) [271498]
- RVO (NL) [271498]
- Gassnova (NO) [271498]
- BEIS (UK) [271498]
- Gassco [271498]
- Equinor [271498]
- European Commission under the Horizon 2020 programme, ACT Grant [691712]
- Swiss Federal Office of Energy (SFOE)
- Total [271498]
- H2020 Societal Challenges Programme [691712] Funding Source: H2020 Societal Challenges Programme
The production of carbon-neutral H-2 is pivotal for reaching net-zero CO2 in 2050. Undoubtedly, the time and scale of this transition call for the decarbonization of H-2 production from natural gas, where the separation processes account for a large share of the capital and operational expenditures. Energy- and cost-efficient processes are therefore highly sought after. With this contribution, we have developed, modeled, and optimized new vacuum pressure swing adsorption (VPSA) cycles for co-production of high-purity, high-recovery CO2 and H-2 from a ternary feed stream with a significant amount of an impurity. We identified two cycles that can purify CO2 up to 95% with recoveries greater 90% while co-producing hydrogen with the same specifications. Key cycle features include purge under vacuum with part of the hydrogen product and recycle of the hydrogen-rich outflow during the initial part of the blowdown. The latter should be carried out via a compressor for very high hydrogen purities and recoveries, or via a sequence of pressure equalization (PE) steps for the targeted separation, which also drastically reduces the energy consumption. The volumetric productivity ranges from 160 to 240 kg(CO2)/m(3)/h, which is significantly larger than the available open data for absorption-based CO2 capture from hydrogen production plants (productivities in the range of 60-90 kg(CO2)/m(3)/h). The energy consumption, when evaluated via exergy to fairly compare heat and electricity, is in the range of state-of-the-art processes (0.5 MJ/kg CO2). Finally, the developed VPSA cycles reduce the separation steps from two to one, which paves the way for further process intensification.
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