Kinetics of Vanillin Hydrodeoxygenation Reaction in an Organic Solvent Using a Pd/C Catalyst

In this work, the kinetics of vanillin (VL) hydrodeoxygenation (HDO) reaction to creosol (CR) over a 10 wt % Pd/C catalyst were studied in a batch autoclave operated at 318-338 K, 1-3 MPa H-2 gas partial pressure, 35-65 mM Initial VL concentration (C-VL0), and 0.13-0.27 kg/m(3) catalyst loading. Experiments were carried out under negligible mass transfer interference which was verified by estimating the observable modulus, minimum stirring speed, and maximum particle size. Additionally, the extent to which the products and acetic acid influences the reaction was examined. Two plausible Langmuir-Hinshelwood-Hougen-Watson (LHHW) models, competitive (Model I) and noncompetitive (Model II) dissociative H-2 adsorption, were discriminated using criteria that a R-2 value greater than 99% indicates adequate fit to the experimental data. Model I emerged as the best fit with a R-2 value greater than 99%. The estimated activation energy was 50.6 kJ/mol, enthalpy of adsorption for H-2 was 28.9 kJ/mol, and VL was 32.5 kJ/mol.