期刊
EUROPEAN POLYMER JOURNAL
卷 118, 期 -, 页码 481-491出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2019.06.026
关键词
Lignocellulose; Ethylene-norbomene copolymer; Silanization; Chemical modification; Composites
In this research lignocellulosic waste is utilized as a filler in ethylene-norbornene copolymer (Topas (R)) matrix. To improve the interface properties between the filler and polymer matrix, lignocellulose was chemically hydrophobized with two coupling agents, namely: vinyltrimethoxysilane (VTMS) and N-(2-aminoethyl)-3-aminopropyltrimethoxysilane (AAPS). Prepared composite samples have been investigated for their thermal and mechanical properties, as well as structure changes. Fourier-transform infrared spectroscopy (FT-IR) analysis revealed that possible bonds recombination within the composite structure may occur - intensity changes in 1100-1000 cm(-1) region (CO-O-CO moieties) and 1300-1200 cm(-2) (-CH3, C=O, C=C bonds). This phenomenon contributed to the observed improvement of composite storage modulus values and performance. Modified lignocellulosic fibres were investigated to assess properties changes which could confirm the silanization occurrence, e.g., increase in thermal stability, hydrodynamic radii enlargement. This research reports the most relevant advances in the field of chemical surface modification of lignocellulose fibres recently achieved by our group.
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