期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2019, 期 36, 页码 6163-6167出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201900726
关键词
Cleavage reactions; Diols; Oxidation; Silanes; Synthetic methods
资金
- Deutsche Forschungsgemeinschaft [ME 776/20-2]
We report a study on diol cleavage of cyclic 1,2-dihydroxysilanes for the preparation of functionalized acylsilanes. Sodium periodate turned out to be an efficient reagent for this transformation, resulting in good to excellent yields. The method is characterized by mild reaction conditions, and sometimes simple aqueous workup of the reaction mixture was sufficient to obtain the acylsilanes in high purity. An acyclic 1,2-dihydroxysilane was readily cleaved as well.
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