A MoS2-Co9S8-NC heterostructure as an efficient bifunctional electrocatalyst towards hydrogen and oxygen evolution reaction

Development of economical, stable and high-efficient electrocatalysts gives vital incentives to promote the large-scale implementation of clean energy devices. Transition metal sulfides and carbon materials provide broad platforms for design of highly active electrocatalysts thanks to their flexibility, high electrical conductivity, and possessing various catalytically active sites towards different reaction systems. Herein, a ternary-component MoS2-Co9S8-NC nanohybrid is synthesized, in which Co9S8, MoS2, and N-doped carbon (NC) are integrated with each other. Owing to forming abundant varied active centers including Co9S8-MoS2 heterojunctions, and Co-N, Mo-N coupling centers locating at the contact interfaces between transition metal sulfides and N-doped carbon, the hybrid demonstrates greatly enhanced performances towards hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Such hybrid represents low overpotentials of 95 mV and 230 mV to achieve 10 mA cm(-2) current density for HER and OER in 1.0 M KOH, respectively, and demonstrates favorable prospects for large-scale applications in overall water splitting. (C) 2019 Elsevier Ltd. All rights reserved.