期刊
DYES AND PIGMENTS
卷 173, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2019.107926
关键词
Semisquaraine; ESIPT; Solid fluorescence; DFT; AIE
资金
- National Natural Science Foundation of China [21363014, 21103082]
- National Science Foundation of the Jiangxi Province of China [20142BCB23003, 20143ACB21021]
Adjusting the emission wavelength and intensity of organic luminogens by precisely manipulating structures has always been a major challenge. In this study, three ABT-based semisquaraines SQ1-3 have been designed and synthesized by trimming the central four-membered ring with ethyoxyl or chloric group. From spectral analysis, all of them exhibited weak emission in dilute solution, but red, yellow to green emission color was verified in their crystal state with Phi(PL) from 0.13, 0.35 to 0.58, respectively. From structural analysis, the increase of electron-deficient chloric groups in SQ3 not only led to more facile ESIPT process and distorted configuration, but also resulted in a rare H-aggregated formation with extremely weak pi-pi interactions in crystalline state, which synergistically facilitated its highest Phi(PL) of 0.58 at shortest emission wavelength of 538 nm. Additionally, typical ESIPT and AIE property was examined and furtherly proved by the TDDFT calculations in all these molecules.
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