期刊
CHINESE JOURNAL OF POLYMER SCIENCE
卷 38, 期 2, 页码 151-157出版社
SPRINGER
DOI: 10.1007/s10118-019-2321-1
关键词
Conjugated microporous polymers; Truxene; Photophysical properties; Gas sorption
资金
- National Natural Science Foundation of China [21574087, 21404074]
- Science and Technology Department of Sichuan Province [2019YJ0128, 2019YFG0277]
Four truxene-based conjugated microporous polymers (Tr-CMPs) were prepared via different synthetic methods and their structure-property relationships were studied. The polymer networks have high Brunauer-Emmett-Teller (BET) specific surface areas ranging from 554 m(2).g(-1) to 1024 m(2).g(-1). Pore sizes of the CMPs with different linkers are mainly located between 0.60 and 1.96 nm. Among all the Tr-CMPs, Tr-CMP4 has the highest BET surface area of 1024 m(2).g(-1) and exhibits the highest H-2 uptake of 0.88 wt%. Tr-CMP2 prepared by Suzuki-Miyaura coupling reaction has the highest photoluminescence quantum yields (PLQYs) of 13.06% and CO2 uptake of 6.25 wt%.
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