期刊
CHINESE CHEMICAL LETTERS
卷 30, 期 8, 页码 1538-1540出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2019.06.049
关键词
Daphniyunnine B; Vicinal quaternary stereocenters; Claisen rearrangement; Intramolecular iodo-amidation reaction
资金
- National Natural Science Foundation of China [21102062, 21472079]
The AC bicyclic skeleton of daphniyunnine B with the required 3. stereocenters (C4, C5 and C8) was accomplished in a concise route which featured two Claisen-type rearrangement reactions to construct the required vicinal all carbon quaternary stereocenters (C5 and C8) and an intramolecular iodocyclization reaction to assemble the cis-confused bicyclic lactam. (C) 2019 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
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