期刊
CHEMSUSCHEM
卷 12, 期 20, 页码 4700-4707出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201901724
关键词
bismuth; carbon dioxide; electrochemistry; formic acid; heterogeneous catalysis
资金
- National Natural Science Foundation of China [21975163]
Mesoporous bismuth nanosheets are prepared through electrochemical transformation of (100)-facet exposed BiOI. Theoretical modeling and calculations are used to simulate the in situ morphological transformation of BiOI into Bi. Mesoporous Bi nanosheets show superior electrochemical CO2 reduction performance. A faradaic efficiency of 95.9 % at -0.77 V-RHE for the conversion of CO2 into formic acid, is achieved for the mesoporous Bi nanosheet catalyst compared with 93.8 % at -0.87 V-RHE for the smooth Bi nanosheets. Tafel analysis and DFT calculations indicate that the electrochemical CO2 reduction on mesoporous Bi nanosheets is kinetically faster with a higher resistance to H-2 generation than that on smooth Bi(001) nanosheets. The CO2-to-HCOOH pathway is preferred through formation of an *OCHO intermediate on the (012) and (001) planes of Bi. The mesoporous structure induces a more accessible interaction with CO2, which makes a predominant contribution to the enhanced performance compared with the subsequent CO2 activation on different facets of Bi.
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